Source apportionment of carbonaceous aerosols using hourly data and implications for reducing PM2.5 in the Pearl River Delta region of South China

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dc.contributor.author
Huang, Junjun
Zhang, Zhisheng
Tao, Jun
Zhang, Leiming
Nie, Fuli
Fei, Leilei
dc.date.accepted
2022-02-12
dc.date.accessioned
2024-08-06T13:57:28Z
dc.date.available
2024-08-06T13:57:28Z
dc.date.issued
2022-02-19
dc.date.submitted
2021-10-07
dc.description.abstract - en
Ambient fine particulate matter (PM<sub>2.5</sub>) levels in South China have been decreasing in the past decade, but the decreasing rates differed between its major chemical components, e.g., with much small rates for carbonaceous aerosols than for secondary inorganic aerosols. To investigate the sources of carbonaceous aerosols in this region, a comprehensive campaign was carried out in urban Guangzhou in the winter of 2019-2020 using a combination of various instruments. Data generated from this campaign include hourly total carbon (TC), black carbon (BC), criteria air pollutants and meteorological parameters, 4-hourly particle-bound elements, and chemically-resolved daily PM<sub>2.5</sub>. Similar diurnal patterns were observed for TC, CO and NO<sub>2</sub>, suggesting TC was very likely related to vehicle exhaust emission. Secondary organic carbon (SOC) estimated using the Minimum R squared (MRS) method accounted for 35±17% of OC, indicating strong atmospheric oxidation capacity. Four major source factors for carbonaceous aerosols were identified by positive matrix factorization (PMF) model, including coal combustion, traffic emissions, soil dust and ship emissions, which accounted for 37±23%, 39±23%, 14±10% and 10±13%, respectively, of TC mass concentration, 38±24%, 38±23%, 14±10% and 10±12%, respectively, of OC mass concentration, and 29±21%, 43±22%, 14±11% and 14±15%, respectively, of EC mass concentration. Among these sources, traffic emission was the most important one, suggesting the necessity for promoting clean energy vehicles and relieving urban traffic congestion.
dc.identifier.issn
0013-9351
1096-0953
dc.identifier.uri
https://open-science.canada.ca/handle/123456789/2806
dc.language.iso
en
dc.publisher
Elsevier
dc.relation.isreplacedby
https://doi.org/10.1016/j.envres.2022.112960
dc.relation.replaces
https://open-science.canada.ca/handle/123456789/2491
dc.rights - en
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
dc.rights - fr
Creative Commons Attribution - Pas d'utilisation commerciale - Pas de modification 4.0 International (CC BY-NC-ND 4.0)
dc.rights.openaccesslevel - en
Green
dc.rights.openaccesslevel - fr
Vert
dc.rights.uri - en
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.uri - fr
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.fr
dc.subject - en
Nature and environment
Science and technology
dc.subject - fr
Nature et environnement
Sciences et technologie
dc.subject.en - en
Nature and environment
Science and technology
dc.subject.fr - fr
Nature et environnement
Sciences et technologie
dc.title - en
Source apportionment of carbonaceous aerosols using hourly data and implications for reducing PM2.5 in the Pearl River Delta region of South China
dc.type - en
Accepted manuscript
dc.type - fr
Manuscrit accepté
local.acceptedmanuscript.articlenum
112960
local.article.journaltitle
Environmental Research
local.article.journalvolume
210
local.pagination
37 pages
local.peerreview - en
Yes
local.peerreview - fr
Oui
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