Atmospheric Chemistry of Gaseous Oxidized Mercury at a Coastal Site in Atlantic Canada

Cheng, Irene; Zhang, Leiming; Mao, Huiting; Ye, Zhuyun; Keenan, Robert

doi:https://open-science.canada.ca/handle/123456789/1340

Atmospheric Chemistry of Gaseous Oxidized Mercury at a Coastal Site in Atlantic Canada

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dc.contributor.author: Cheng, Irene; Zhang, Leiming; Mao, Huiting; Ye, Zhuyun; Keenan, Robert
dc.date.accepted: 2020-01-08
dc.date.accessioned: 2023-12-07T20:57:49Z
dc.date.available: 2023-12-07T20:57:49Z
dc.date.issued: 2020-03-01
dc.date.submitted: 2019-05-06
dc.description.abstract - en: A chemistry box model containing a comprehensive suite of mercury (Hg) oxidation mechanisms involving O3, OH, H2O2, Br, BrO, NO2, HO2, and other oxidants was used to simulate the formation of gaseous oxidized mercury (GOM) and understand the chemical processes driving the observed trends in GOM at Kejimkujik, Nova Scotia, Canada. Simulations were conducted using chemical schemes with and without oxidation by O3 and OH. The major oxidants of Hg are O3 and OH (79%), H2O2 (10%), Br with second-stage HgBr oxidation by NO2 (7%), and BrO (3%) in simulations where all GEM oxidation reactions were considered simultaneously. In an alternative chemical scheme without gas-phase oxidation by O3 and OH, the dominant GOM species were HgBrNO2 (58%) and HgBrO (23.5%). Using this chemical scheme, the model reproduced the observed GOM at sub-ppqv Br2 mixing ratios. In the scheme with O3 and OH, the variability in GOM between seasons and between continental and marine air masses was mainly due to the variability in gaseous elemental Hg, O3, OH, and aerosol liquid water content (LWC). LWC governs the partitioning of GOM to the aerosol aqueous phase in the model. In the scheme without O3 and OH, the variability in GOM by season and airmass origin strongly depends on Br and BrO, suggesting that rigorous validation of modeled Br and BrO data are essential for improving the model predictions of GOM in coastal environments.
dc.description.fosrcfull - en: Copyright [2020] American Meteorological Society (AMS). For permission to reuse any portion of this Work, please contact <a href = "mailto: permissions@ametsoc.org">permissions@ametsoc.org</a>. Any use of material in this Work that is determined to be “fair use” under Section 107 of the U.S. Copyright Act (17 U.S. Code § 107) or that satisfies the conditions specified in Section 108 of the U.S. Copyright Act (17 USC § 108) does not require the AMS’s permission. Republication, systematic reproduction, posting in electronic form, such as on a website or in a searchable database, or other uses of this material, except as exempted by the above statement, requires written permission or a license from the AMS. All AMS journals and monograph publications are registered with the Copyright Clearance Center (<a href="https://www.copyright.com">https://www.copyright.com</a>). Additional details are provided in the AMS Copyright Policy statement, available on the AMS website (<a href="https://www.ametsoc.org/PUBSCopyrightPolicy">https://www.ametsoc.org/PUBSCopyrightPolicy</a>)
dc.description.fosrcfull-fosrctranslation - fr: Droit d'auteur [2020] American Meteorological Society (AMS). Pour obtenir l'autorisation de réutiliser toute partie de cette œuvre, veuillez contacter <a href = "mailto: permissions@ametsoc.org">permissions@ametsoc.org</a>. Toute utilisation d'un élément de cette œuvre considérée comme une "utilisation équitable" par l'article 107 de la loi américaine sur le droit d'auteur (U.S. Copyright Act, 17 U.S. Code § 107) ou satisfaisant aux conditions énoncées à l'article 108 de la loi américaine sur le droit d'auteur (U.S. Copyright Act, 17 U.S. Code § 108) ne requiert pas l'autorisation de l'AMS. La republication, la reproduction systématique, l'affichage sous forme électronique, par exemple sur un site web ou dans une base de données interrogeable, ou toute autre utilisation de ce matériel, à l'exception de ce qui est exempté par la déclaration ci-dessus, nécessite une autorisation écrite ou une licence de la part de l'AMS. Toutes les revues et monographies de l'AMS sont enregistrées auprès du Copyright Clearance Center (<a href="https://www.copyright.com">https://www.copyright.com</a>). Des détails supplémentaires sont prévu dans la déclaration de politique de droit d'auteur de l'AMS, disponible sur le site web de l'AMS (<a href="https://www.ametsoc.org/PUBSCopyrightPolicy">https://www.ametsoc.org/PUBSCopyrightPolicy</a>)
dc.identifier.doi: https://doi.org/10.1175/JAS-D-19-0120.1
dc.identifier.issn: 0022-4928; 1520-0469
dc.identifier.uri: https://open-science.canada.ca/handle/123456789/1340
dc.language.iso: en
dc.publisher: American Meteorological Society
dc.rights.openaccesslevel - en: Green
dc.rights.openaccesslevel - fr: Vert
dc.subject - en: Air; Nature and environment; Science and technology
dc.subject - fr: Air; Nature et environnement; Sciences et technologie
dc.subject.en - en: Air; Nature and environment; Science and technology
dc.subject.fr - fr: Air; Nature et environnement; Sciences et technologie
dc.title - en: Atmospheric Chemistry of Gaseous Oxidized Mercury at a Coastal Site in Atlantic Canada
dc.type - en: Article
dc.type - fr: Article
local.article.journalissue: 3
local.article.journaltitle: Journal of the Atmospheric Sciences
local.article.journalvolume: 77
local.pagination: 1137–1149
local.peerreview - en: Yes
local.peerreview - fr: Oui
local.requestdoi: No

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