Fine particulate pollution driven by nitrate in the moisture urban atmospheric environment in the Pearl River Delta region of south China

Abstract

To identify potential sources of fine particles (PM_2.5, with aerodynamic diameter (D_a) ≤ 2.5 μm) in urban Dongguan of south China, a comprehensive campaign was carried out in the whole 2019. Hourly PM_2.5 and its dominant chemical components including organic carbon (OC), elemental carbon (EC), water-soluble inorganic ions (WSIIs) and thirteen elements were measured using online instruments. Gaseous pollutants including NH₃, HNO₃, NO₂, NO and O₃ and meteorological parameters were also synchronously measured. PM_2.5 was dominated by carbonaceous aerosols in summer and by WSIIs in the other seasons. PM_2.5 and its dominant chemical components mostly peaked around noon (10:00-14:00 LST). Furthermore, high PM_2.5 levels during the daytime were closely related with the increased NO₃^- levels. The high mass concentrations of NO₃^- in urban Dongguan during the daytime were likely related with regional transport of NO₃^- from suburban Dongguan, which was originated from the reaction between NO₂ and O₃ under the moisture condition during the nighttime. Seven major source factors for PM_2.5 including secondary sulfate, ship emission, traffic emission, secondary nitrate, industrial processes, soil dust and coal combustion were identified by positive matrix factorization (PMF) analysis, which contributed 26±14%, 16±16%, 16±10%, 14±11%, 12±11%, 8±6% and 8±6%, respectively, to annual PM_2.5 mass concentration. Although secondary sulfate contributed much more than secondary nitrate to PM_2.5 on annual basis, the latter exceeded the former source factor when daily PM_2.5 mass concentration was higher than 60 μg m^-3, indicating the critical role nitrate played in PM_2.5 episode events.