Canola meal valorization via acid hydrolysis to generate free amino acids

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creativework.keywords - en
canola meal
proteins
ethanol pre-treatment
free amino acids
response surface methodology
hydrology
creativework.keywords - fr
tourteau de colza canola
prétraitement à l'ethanol
protéines
acides aminés libre
méthode de surface de réponse
hydrolyse
dc.contributor.author
Warnakulasuriya, Sumudu N.
Tanaka, Takuji
Wanasundara, Janitha P. D.
dc.date.accepted
2023-08-11
dc.date.accessioned
2024-07-30T21:37:03Z
dc.date.available
2024-07-30T21:37:03Z
dc.date.issued
2023-09-22
dc.date.submitted
2023-06-06
dc.description.abstract - en
This study investigated an alternative approach to valorizing canola proteins by hydrolyzing them to generate amino acids (AAs). Pre-treatment of cold-pressed (CP) cake and desolventized-toasted (DT) meal with ethanol (99%, vol/vol) followed by protein separation was studied as process optimizations to maximize protein recovery with higher purity. The optimum ethanol pre-treatment conditions to achieve a meal containing less than 1% oil was reached at a meal-to-ethanol ratio of 1:4 (wt:wt) and 50°C for 30 min extraction. The protein recovery reached the maximum at pH 12 and a meal-to-solvent ratio of 1:10 (wt:vol), yielding 73% and 33% recovery from ethanol pre-treated CP and DT meals, respectively, in a single extraction. Untreated and ethanol pre-treated meals were hydrolyzed with 6 N HCl (protein-to-acid ratio of 5 mg:2 mL) for 24 h at 110°C. The ethanol pre-treatment improved AA recovery and released 373 mg AA/g dry CP meal biomass (dbm) compared to 279 mg AA/g untreated CP cake dbm. However, no improvement in AA recovery upon ethanol pre-treatment of DT meal. Sulfuric acid was examined as an alternative acid. More than 700 mg AA/g CP protein were released with 6 N H2SO4, while for DT meal proteins, a 10 N concentration was needed to achieve a closer value. Commercial canola meals can be utilized for generating free AAs; however, the meal processing history may affect the yield.
dc.identifier.citation
Warnakuluasuriya, S. N., Tanaka, T., & Wanasundara, J. P. D. (2024). Canola meal valorization via acid hydrolysis to generate free amino acids. Journal of the American Oil Chemists' Society, 101, 41-57. https://doi.org/10.1002/aocs.12739
dc.identifier.doi
https://doi.org/10.1002/aocs.12739
dc.identifier.issn
1558-9331
0003-021X
dc.identifier.uri
https://open-science.canada.ca/handle/123456789/2772
dc.language.iso
en
dc.publisher
Wiley Periodicals LLC, AOCS
dc.rights - en
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
dc.rights - fr
Creative Commons Attribution - Pas d'utilisation commerciale - Pas de modification 4.0 International (CC BY-NC-ND 4.0)
dc.rights.uri - en
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.uri - fr
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.fr
dc.subject - en
Agriculture
Science and technology
dc.subject - fr
Agriculture
Sciences et technologie
dc.subject.en - en
Agriculture
Science and technology
dc.subject.fr - fr
Agriculture
Sciences et technologie
dc.title - en
Canola meal valorization via acid hydrolysis to generate free amino acids
dc.type - en
Article
dc.type - fr
Article
local.article.journaltitle
Journal of the American Oil Chemists' Society
local.article.journalvolume
101
local.pagination
41-57
local.peerreview - en
Yes
local.peerreview - fr
Oui
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