Total organic carbon measurements reveal major gaps in petrochemical emissions reporting

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dc.contributor.author
He, Megan
Ditto, Jenna C.
Gardner, Lexie
Machesky, Jo
Hass-Mitchell, Tori N.
Chen, Christina
Khare, Peeyush
Sahin, Bugra
Fortner, John D.
Plata, Desiree L.
Drollette, Brian D.
Hayden, Katherine L.
Wentzell, Jeremy J.B.
Mittermeier, Richard L.
Leithead, Amy
Lee, Patrick
Darlington, Andrea
Wren, Sumi N.
Zhang, Junhua
Wolde, Mengistu
Moussa, Samar G.
Li, Shao-Meng
Liggio, John
Gentner, Drew R.
dc.date.accepted
2023-12-15
dc.date.accessioned
2024-09-12T13:23:30Z
dc.date.available
2024-09-12T13:23:30Z
dc.date.issued
2024-01-26
dc.date.submitted
2023-07-13
dc.description.abstract - en
Anthropogenic organic carbon emissions reporting has been largely limited to subsets of chemically-speciated volatile organic compounds. However, novel aircraft-based measurements revealed total organic carbon emissions exceeding oil sands industry-reported values by 1900-6300%, the bulk of which was due to unaccounted-for intermediate- and semi-volatile organic compounds. Measured facility-wide emissions represented approximately 1% of extracted petroleum, resulting in total organic carbon emissions equivalent to that from all other sources across Canada combined. These real-world observations demonstrate total organic carbon measurements as a means of detecting unknown or underreported carbon emissions regardless of chemical features. Since reporting gaps may include hazardous, reactive, or secondary air pollutants, fully constraining the impact of anthropogenic emissions necessitates routine, comprehensive total gaseous organic carbon monitoring as an inherent check on mass closure.
dc.description.fosrcfull - en
This is the author’s version of the work. It is posted here by permission of the AAAS for personal use, not for redistribution. The definitive version was published in Science on Volume 383, January 2024, DOI:10.1126/science.adj6233
dc.description.fosrcfull-fosrctranslation - fr
Ceci est le manuscrit accepté de l'auteur. Il est publié ici avec l'autorisation de l’AAAS pour un usage personnel et non pour la redistribution. La version finale a été publiée dans Science le Volume 383, janvier 2024, DOI : 10.1126/science.adj6233
dc.identifier.issn
1095-9203
0036-8075
dc.identifier.uri
https://open-science.canada.ca/handle/123456789/2934
dc.language.iso
en
dc.publisher
American Association for the Advancement of Science
dc.relation.isrelatedto
https://donnees.ec.gc.ca/data/air/monitor/ambient-air-quality-oil-sands-region/pollutant-transformation-aircraft-based-multi-parameters-oil-sands-region/?lang=en
dc.relation.isreplacedby
https://doi.org/10.1126/science.adj6233
dc.rights.openaccesslevel - en
Green
dc.rights.openaccesslevel - fr
Vert
dc.subject - en
Nature and environment
Science and technology
dc.subject - fr
Nature et environnement
Sciences et technologie
dc.subject.en - en
Nature and environment
Science and technology
dc.subject.fr - fr
Nature et environnement
Sciences et technologie
dc.title - en
Total organic carbon measurements reveal major gaps in petrochemical emissions reporting
dc.type - en
Accepted manuscript
dc.type - fr
Manuscrit accepté
local.article.journalissue
6681
local.article.journaltitle
Science
local.article.journalvolume
383
local.pagination
16 pages
local.peerreview - en
Yes
local.peerreview - fr
Oui
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