Applications of ultrahigh performance liquid chromatography electrospray ionization Q-Orbitrap mass spectrometry and QuEChERS for fingerprinting and identification of molecular markers in orange juices

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dc.contributor.author
Wang, Jian
Chow, Willis
dc.date.accepted
2023-03-06
dc.date.accessioned
2023-10-27T19:47:32Z
dc.date.available
2023-10-27T19:47:32Z
dc.date.issued
2023-03-16
dc.date.submitted
2022-12-23
dc.description.abstract - en
This study explored the use of UHPLC/ESI Q-Orbitrap HRMS-based nontarget metabolomics and QuEChERS for fingerprinting and profiling of orange juices for purposes of assessing authenticity and consumer protection. UHPLC/ESI Q-Orbitrap Full MS and Full MS/dd-MS2 (TopN) data allowed for principle component analysis (PCA), clustering, and differential analysis, and identification of molecular markers. By differential analysis, orange juices made “From Concentrate” (FCs) and “Not From Concentrate” (NFCs) were distinguished in the PCA score plot. Common citrus flavonoids such as tangeretin, nobiletin, hesperidin, and narirutin from orange juices were identified. Steviol glycosides (stevioside and rebaudioside A) were also identified in orange juice/beverage in which stevia extracts had been added as sweeteners. The use of UHPLC/ESI Q-Orbitrap and QuEChERS was practical to distinguish FCs and NFCs, and identify citrus flavonoids and other molecular markers. The identified markers can be used to develop quantitative methods and establish their benchmarks for orange juice authentication and quality.
dc.identifier.citation
Wang, J., & Chow, W. (2023). Applications of ultrahigh performance liquid chromatography electrospray ionization Q-Orbitrap mass spectrometry and QuEChERS for fingerprinting and identification of molecular markers in orange juices. ACS Food Science & Technology, 3(4), 729–737. https://doi.org/10.1021/acsfoodscitech.2c00438
dc.identifier.doi
https://doi.org/10.1021/acsfoodscitech.2c00438
dc.identifier.issn
2692-1944
dc.identifier.uri
https://open-science.canada.ca/handle/123456789/1255
dc.language.iso
en
dc.publisher
American Chemical Society
dc.rights - en
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.rights - fr
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.rights.openaccesslevel - en
Gold
dc.rights.openaccesslevel - fr
Or
dc.rights.uri - en
https://creativecommons.org/licenses/by/4.0/
dc.rights.uri - fr
https://creativecommons.org/licenses/by/4.0/deed.fr
dc.subject - en
Science and technology
dc.subject - fr
Sciences et technologie
dc.subject.en - en
Science and technology
dc.subject.fr - fr
Sciences et technologie
dc.title - en
Applications of ultrahigh performance liquid chromatography electrospray ionization Q-Orbitrap mass spectrometry and QuEChERS for fingerprinting and identification of molecular markers in orange juices
dc.type - en
Accepted manuscript
dc.type - fr
Manuscrit accepté
local.article.journalissue
4
local.article.journaltitle
ACS Food Science & Technology
local.article.journalvolume
3
local.pagination
729-737
local.peerreview - en
Yes
local.peerreview - fr
Oui
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